Xiangfeng Shao

Introduction

Xiangfeng Shao received the B.S. and M.S. degrees (majored in organic chemistry) from Lanzhou University in the years of 1998 and 2001, respectively. He then joined Prof. Daoben Zhu’s group at the Institute of Chemistry, Chinese Academy of Sciences as a Ph. D. candidate and performed research in the field of organic functional materials. He got the Ph. D. in the year of 2004, and thereafter worked as a post-doc in Japan Science and Technology Agency (JST), Kyoto University, and Osaka Prefecture University until 2009. During this period, he mainly focused on the field-induced phase transitions of organic conductors and exploration of magnetic organic conductors. In October 2009, he became a professor of chemistry at Lanzhou University. His current research includes the design, synthesis, chemical reactivity, optoelectronic property, and self-assembly of non-conventional π-conjugated systems. He received the Excellent Youth Fund from NSFC in 2015 and appointed as the vice-director of SKLAOC in 2018.


Representative Publications

1. S. Wang, C. Yan, J. Shang, W. Wang, C. Yuan, H.-L. Zhang, X. Shao*; Doping Sumanene with both Chalcogen and Phosphorus(V): One-Step Synthesis, Coordination and Selective Response toward Ag(I); Angew. Chem. Int. Ed.,2019, 58, 3819–3823.

2. S. Wang, J. Shang, C. Yan, W. Wang, C. Yuan*, H.-L. Zhang, X. Shao*; Trichalcogenasumanenes Containing various Chalcogen Atoms: Synthesis, Structure, Property, and Chemical Reactivity; Org. Chem. Front.,2019, 6, 263–272.

3. Y.-P. Zhang, L.-C. Chen, Z.-Q. Zhang, J.-J. Cao, C. Tang, J. Liu, L.-L. Duan, Y. Huo, X. Shao, W. Hong*, H.-L. Zhang*; Distinguishing Diketopyrrolopyrrole Isomers in Single-Molecule Junctions via Reversible Stimuli-Responsive Quantum Interference; J. Am. Chem. Soc., 2018, 140, 6531–6535.

4. J. Sun,* Y. Sun, C. Yan, D. Lin, Z. Xie, S. Zhou, C. Yuan,* H.-L. Zhang, X. Shao*; Remarkable Nonlinear Optical Response of Pyrazine-fused Trichalcogenasumanenes and Their Application for Optical Power Limiting (2018 HOT Paper); J. Mater. Chem. C,2018, 6, 13114–13119.

5. J. Sun, B. Yuan, X. Hou, C. Yan, X. Sun, Z. Xie*, X. Shao*, S. Zhou; Broadband Optical Limiting of Novel Twisted Tetrathiafulvalene Incorporated Donor-Acceptor Material and Their Ormosil Gel Glasses; J. Mater. Chem. C,2018, 6, 8495–8501.

6. X. Hou, J. Sun*, Z. Liu, C. Yan, W. Song, H.-L. Zhang, S. Zhou, X. Shao*; Opening Two Benzene Rings on Trichalcogenasumanenes toward High Performance Organic Optical-Limiting Materials; Chem. Commun.,2018, 54, 10981–10984;

7. R. Geng, X. Hou, Y. Sun, C. Yan, Y. Wu, H.-L. Zhang, X. Shao*; Driving π-plane to π-bowl through the lateral coordination at room temperature; Mater. Chem. Front.,2018, 2, 1456–1461.

8. Y. Sun, X. Li, C. Sun, H. Shen, X. Hou, D. Lin, H.-L. Zhang, C.-a. Di, D. Zhu, X. Shao*; Trichalcogenasumanene ortho-Quinones: Synthesis, Properties, and Transformation into Various Hetero Polycycles; Angew. Chem. Int. Ed., 2017, 56, 13470–13474.

9. Z.-H. Wu, Z.-T. Huang, R.-X. Guo, C.-L. Sun, L.-C. Chen, B. Sun, Z.-F. Shi, X. Shao, H. Li*, H.-L. Zhang*; 4,5,9,10-Pyrene Diimides: A Family of Aromatic Diimides Exhibiting High Electron Mobility and Two-Photon Excited Emission; Angew. Chem. Int. Ed., 2017, 56, 13031–13035.

10. Z.-P. Fan, X.-Y. Li, X.-E. Luo, X. Fei, B. Sun, L.-C. Chen, Z.-F. Shi, C.-L. Sun, X. Shao, H.-L. Zhang*; Boosting the Charge Transport Property of Indeno[1,2-b]fluorene-6,12-dione through Incorporation of Sulfur- or Nitrogen-Linked Side Chains; Adv. Funct. Mater., 2017, 27, 1702318.

11. B. Fu, X. Hou, C. Wang, Y. Wang, X. Zhang, R. Li*, X. Shao*, W. Hu; A Bowl-Shaped Sumanene Derivative with Dense Convex-Concave Columnar Packing for High-Performance Organic Field-Effect Transistors; Chem. Commun., 2017, 53, 11407–11409.

12. X. Hou, Y. Zhu, Y.Qin, L. Chen, X. Li, H.-L. Zhang, W. Xu, D. Zhu, X. Shao*; ( contributed equally); Tris(S,S-dioxides)-trithiasumanene: Strong Fluorescence and Cocrystal with 1,2,6,7,10,11-Hexabutoxytriphenylene (HBT); Chem. Commun., 2017, 53, 1546–1549.

13. X. Hou, X. Li, C. Sun, L. Chen, Y. Sun, Z. Liu, H.-L. Zhang, X. Shao*; Dissecting Trichalcogenasumanenes: π-Bowl to Planar, Invertible Curvature, and Chiral Polycycles; Chem. Eur. J., 2017, 23, 14375–14383.

14. S. Wang, X. Li, X. Hou, Y. Sun, X. Shao* (contributed equally); Tritellurasumanene: Ultrasound Assisted One-Pot Synthesis and Extended Valence Adduct with Bromine; Chem. Commun., 2016, 52, 14486–14489.

15. X. Li, Y. Zhu, J. Shao, L. Chen, S.Zhao, B.Wang, S. Zhang, Y. Shao, H.-L. Zhang, X. Shao* (contributed equally); Ring Reconstruction on a Trichalcogenasumanene Buckybowl: A Facile Approach to Create Donor-Acceptor Type [5-6-7]-Fused Planar Polyheterocycles; Angew. Chem. Int. Ed., 2015, 54, 267–271.

16. X. Li, Y. Zhu, J. Shao, B. Wang, S. Zhang, Y. Shao, X. Jin, X. Yao, R. Fang, X. Shao*; Non-Pyrolytic, Large-Scale Synthesis of Trichalcogenasumanene: A Two-Step Approach; Angew. Chem. Int. Ed., 2014, 53, 535–538.

17. J. Sun, X. Lu, M. Ishikawa, Y. Nakano, S. Zhang, J. Zhao, Y. Shao, Z. Wang, H. Yamochi, X. Shao*; Inclusion Complexes of Fullerenes with Flexible Tetrathiafulvalene Derivatives Bearing Four Aryls through the Sulfur Bridges; J. Mater. Chem. C, 2014, 2, 8071–8076.

18. X. Lu, J. Sun, Y. Liu, J. Shao, L. Ma, S. Zhang, J. Zhao, Y. Shao, H.-L. Zhang, Z. Wang, X. Shao*; Decorating Tetrathiafulvalene (TTF) with Fluorinated-Phenyls through Sulfur Bridges: Facile Synthesis, Properties, and Aggregation via Fluorine Interaction; Chem. Eur. J., 2014, 20, 9650–9656.

19. J. Sun, X. Lu, J. Shao, X. Li, S. Zhang, B. Wang, J. Zhao, Y. Shao, R. Fang, Z. Wang, W. Yu, X. Shao*; Molecular and Crystal Structure diversity, and Physical Properties of Tetrathiafulvalene Derivatives Substituted with Various Aryls through Sulfur Bridges; Chem. Eur. J., 2013, 19, 12517–12525.

20. M. Gao, C. Lu, H. Jean-Ruel, L. C. Liu, A. Marx, K. Onda, S.-y. Koshihara, Y. Nakano, X. Shao, T. Hiramatsu, G. Saito, H. Yamochi, R. R. Cooney, G. Moriena, G. Sciaini, R. J. D. Miller; Mapping Molecular Motions Leading to Charge Delocalization with Ultrabright Electrons; Nature, 2013, 496, 343–346.

 


Office:

Room 4037, the First Chemistry Building

TEL:

0931-8912500

E-mail:

shaoxf@lzu.edu.cn

Education:

19941998, Lanzhou University, B.S.

19982001, Lanzhou University, M.S.

20012004, Institute of Chemistry, Chinese Academy of Sciences, Ph.D.